By G. Graner, E. Hirota, T. Iijima, K. Kuchitsu, D.A. Ramsay, J. Vogt, N. Vogt
Volume II/28 is a supplemented and revised variation of the previous volumes II/7, II/15, II/21, II/23 and II/25, containing modern details at the geometric parameters (internuclear distances, bond angles, dihedral angles of inner rotation etc.) of unfastened inorganic and natural polyatomic molecules. All experimental equipment for the choice of quantitative structural info of unfastened molecules were thought of: microwave, infrared, Raman, digital and photoelectron spectroscopy in addition to electron diffraction. the knowledge acquired through those tools were seriously evaluated and compiled. they're offered individually for every molecule, including a computer-drawn schematic determine of the constitution and the unique literature.
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I-V, 1964-1969. A. Guarnieri, P. Favero: "Microwave Gas Spectroscopy Bibliography", Inst. Chimico G. Ciamician, Univ. di Bologna ,1968. D. W. L. H. A. J. J. G. Maki: J. Phys. Chem. Ref. Data 8 (1979) 619. 3 Infrared, Raman and electronic spectroscopy Books I-1 I-2 I-3 I-4 I-5 I-6 I-7 I-8 I-9 I-10 I-11 I-12 I-13 I-14 I-15 G. Herzberg: "Molecular Spectra and Molecular Structure I. Spectra of Diatomic Molecules", Malabar, FL: Krieger, 1989; "II. Infrared and Raman Spectra of Polyatomic Molecules", ibid.
Boggs, in: Reference E-8, Part B, Chap. 10. M. Hargittai, I. Hargittai: Int. J. Quantum Chem. 44 (1992) 1057. P. Spiridonov, N. Vogt, J. Vogt: Struct. Chem. 12 (2001) 349. S. Mastryukov: "Electron Diffraction: A Combination with Other Techniques" in: Reference G-4, Chap. 2. 1 List of symbols A, B, C ,B ,A ,C X Rotational constants (see Sect. 1) Labels for electronic states, ground state labeled X a , b , c ,... Y = nonbonded distance) Distance between equilibrium nuclear positions Distance between average nuclear positions (ground vibrational state, υ1 = υ2 " = 0) rα r0 Distance between average nuclear positions (thermal equilibrium) Distance between effective nuclear positions derived from rotational constants of zero-point vibrational level (υ1 = υ2 " = 0) Distance between effective nuclear positions derived from isotopic differences in rotational constants Distance between effective nuclear positions derived from the mass-dependence method of Watson, very close to re for molecules without hydrogen atoms Distance obtained by a slightly modified method of Harmony et al.
Robertson, in: "Spectroscopic Properties of Inorganic and Organometallic Compounds", Specialist Periodical Reports, G. V. G. H. H. E. , 22 (1989) 462; 23 (1990) 471; 24 (1991) 470; 25 (1992) 433; 26 (1993) 463; 27 (1994) 438; 28 (1995) 428; 29 (1996) 418; 30 (1997) 454; 31 (1998) 436; 32 (1999) 370; 33 (2000) 500; 34 (2001) 377; 35 (2002) 339. H. R. P. ), London: Royal Society of Chemistry, 1991, 253. I. Hargittai, in: "Static and Dynamic Implications of Precise Structural Information, Lecture Notes", A.